9910114v1

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Perturbation method with triangular propagators and anharmonicities of intermediate strength

Miloslav Znojil

abstract: I propose a new version of the Rayleigh - Schr\"{o}dinger perturbation method. It admits a lower triangular matrix in place of the usual diagonal propagator. Illustrated on rational anharmonicities polynomial}(x)/polynomial}(x), treated as perturbations of (quasi-)exact anharmonic oscilators. In this sense the method works in an intermediate-coupling regime and bridges the gap between the weak- and strong-coupling expansions.

oai_identifier:
oai:arXiv.org:quant-ph/9910114
categories:
quant-ph
comments:
37 pages (Latex file, incl. 6 tables) plus 6 ps file figures, to be submitted to J. Math. Chem
arxiv_id:
quant-ph/9910114
journal_ref:
J. Math. Chem. 28 (2000) 139 - 167.
created:
1999-10-27

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